Researchers Improve Solar Capture with Materials that Enhance Scattering of Light
September 11, 2013 6:30 AM
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Nanostructures with different photoconduction properties
(Source: University of Pennsylvania)
The process can also be customized for different applications
Researchers have found a new technique of collecting energy from light for
improved solar energy harvesting
, which could lead to better optoelectronic devices.
Researchers from the University of Pennsylvania -- led by Dawn Bonnell, Penn's vice provost for research and Trustee Professor of Materials Science and Engineering in the School of Engineering and Applied Science -- have used plasmonic structures and a technique called ferroelectric nanolithography to make a process more efficient than conventional photoconduction.
The study is based on Bonnell and colleagues' previous work from 2010. At that time
they reported the fabrication of a plasmonic nanostructure that induced and projected an electrical current across molecules. Plasmons are a collective oscillation of electrons. Ferroelectric nanolithography was used to design the material, which is an array of gold nanoparticles that tends to get plasmons excited due to optical radiation.
However, the team couldn't exactly prove that the improved transduction of optical radiation to an electrical current was due to excited plasmons creating hot electrons.
"We hypothesized that, when plasmons are excited to a high energy state, we should be able to harvest the electrons out of the material," said Bonnell. "If we could do that, we could use them for molecular electronics device applications, such as circuit components or solar energy extraction."
Now, in the latest study, Bonnell and the team varied the the size of the gold nanoparticles, the size of the porphyin molecules and the spacing of those components. They also designed certain structures that ruled out other possibilities so that the enhanced photocurrent could only be from the hot electrons harvested from the plasmons.
The materials fabricated from gold particles and light-sensitive molecules of porphyin (which consisted of precise sizes and were arranged in specific patterns) made the plasmons excited by optical radiation and caused them to induce an electrical current that can move in a pattern determined by the size and arrangement of the gold particles, as well as the electrical properties of the environment. These materials can enhance the scattering of light and can increase absorption in solar cells.
By changing the size and spacing of nanoparticles, the wavelength of light to which the plasmon responds is adjusted. This means the process can be customized.
The results found increases of three to 10 times in the efficiency through the use of plasmons and ferroelectric nanolithography compared to conventional photoexcitation.
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now if we only had better storage of the big "E"
9/11/2013 12:11:20 PM
Our biggest problem today's world is Energy Storage.
Energy storage is always a big problem when harvesting it. Aka solar, nuclear, hydro-electric, etc etc.
Energy is conductive and storing conductive is difficult to maintain over time as = heat, and heat temps rise and cool and keeping that in check for long term use, just is not in place in our current technology.
Gas = easier to store longer, and can be used on demand turn on or off, but it has pitfalls also as we all know, but battery systems, are just to short to be viable. For the ever modern demand of energy use people are asking for today vs the amounts of 10 to 20 years ago, was 30x less.
"We basically took a look at this situation and said, this is bullshit." -- Newegg Chief Legal Officer Lee Cheng's take on patent troll Soverain
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