A team of Yale chemists accepted the challenge from the Department of Energy search for a way to distill sunlight into liquid fuel.
The Yale researchers will join 12 other institutions in attempting to create an affordable photocatalytic cell for water cleavage with visible light power. The goal of the $12.8 million DOE Solar Energy to Chemical Fuels Initiative is to create economically viable fuels suitable for use in transportation.
If the effort should prove successful, one of the major achievements will be to "overcome the problem of day/night variation of the solar resource,” according to a statement from the Yale Department of Chemistry.
"This has been a goal of photoelectrochemistry research for more than three decades," said Yale’s project leader and department chair, Professor Gary Brudvig. "Our challenge is to improve efficiency of solar energy utilization.”
The Yale team will focus on attaching manganese complexes to titanium dioxide nanoparticles. In the process, the team plans to develop a comprehensive understanding of the molecular-level structural and dynamic principles underlying photocatalytic devices.