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WSU chemistry professor Choong-Shik Yoo (second from right) with the "Yoo Group"  (Source: WSU)
Most powerful material that isn't nuclear energy

Washington State University researchers have recently discovered a compact, high-pressure,unknown material with the ability to store large amounts of energy. It is the most condensed and powerful form of energy that is non-nuclear, and could create a whole new class of energetic materials or fuels.

This study, titled "Two- and three-dimensional extended solids metalization of compressed XeF2," has been published in the journal Nature Chemistry and was led by Washington State chemistry professor Choong-Shik Woo. 

The researchers created this super energy material by combining fluoride, xenon, and pressures comparable to those found in the center of the Earth. Xenon difluoride (XeF2), a white crystal that etches silicon conductors, was put into a two-inch by three-inch diameter device called a diamond anvil cell. This device embraces the crystal, "squeezing" it between to diamond anvils and produces high pressures within a small space.

The material's molecules stayed far apart from one another under normal atmospheric pressure, but as researchers increased the pressure, these molecules came closer together resulting in a two-dimensional semiconductor. At the two-dimensional level, the material turns into a red, graphite-like structure that transforms from XeF2 to XeF4. This occurs around 50 GPa, but when the researchers increased the pressure to 70 GPa, XeF4 then transforms into a three-dimensional, black structure resembling the metallic XeF8 polyhedron. 

But the increase in pressure didn't stop there. Researchers continued raising the pressure inside the diamond anvil cell until it reached pressures seen only near the center of the Earth. This caused the molecules to create "tightly-bound three-dimensional metallic network structures," and inside these bonds stored the chemical energy from the large amount of mechanical energy of compression. There was a total of one million atmosphere's of stored energy.  

What this produces is an incredibly powerful battery that is one step below the nuclear energy category. This new material could be used as an energy storing device, a superconductor and to super-oxidize materials that can destroy chemical and biological agents. 



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Energy Storage and Superconducting Material?
By 3DoubleD on 7/6/2010 8:56:54 AM , Rating: 5
I read the cited paper, which was very interesting on its own, and I fail to see how the journalists arrived at the conclusion that this is an energy storage AND superconducting material (which already seems ridiculous just saying that).

The only way I can imagine this material becoming an energy storage device is by using it as a "spring". You can load the spring by putting pressure on it and once you let go, it could possibly return the force as it returns to it's equilibrium state. In the cited paper, the authors describe the material returning to it's equilibrium state very quickly with minimal hysteresis (unlike materials like diamond, which transforms to graphite extremely slowly). So perhaps there is hope that a material like this could be used to store energy in a power plant setting. It certainly would not replace a portable battery. However, this idea was not in the original paper, so it's purely an attempt by me to rationalize the claims made in this news article.

Furthermore, it was noted by the authors of the paper that the material exhibited a change from insulator to metal. There is no mention of any superconductivity (measurements or results). I'm not sure where the journalists arrived at this conclusion.

Cool science though. I had no idea new materials could be formed from high Z noble gases.




By DrizztVD on 7/6/2010 9:44:09 AM , Rating: 5
While the paper is interesting from a scientific viewpoint, there is nothing exciting about the findings. It simply proves what is already known- that the Xe valence electrons will reconfigure in the correct thermodynamic environment to form eight bonds to Flourine.

The sensational statements about battery and semiconductor application is nonsense. The energy stored in this way as simple mechanical energy and you would get basically the same storage potential from compressing water. - or more correctly a polymorphic (unit cell changing) material, which is common. The author shows a lack of insight in the huge engineering challenges involved in realizing scientific findings into commercial products, never mind the fact that this research has no real application to speak of.

It's a chemistry finding that supports the theory of hybridization and octet forming in compound bonding, nothing more. What's more, the original author probably knows this and just wanted to find out how gullible people are- which is probably why you can't find where he got the superconductor reference from.


By NARC4457 on 7/6/2010 12:13:48 PM , Rating: 2
I'm guessing the author meant supercapacitor instead of superconductor.

Of course I didn't read the paper, but it makes sense in context of the article.


Please Develop This For a Battery
By gigahertz20 on 7/6/2010 7:51:24 AM , Rating: 4
Now future iPhone 6's can have 1,377 hours of battery time, just don't hold the battery wrong or you could set off a sub-nuclear explosion!




By FaceMaster on 7/6/2010 8:20:20 AM , Rating: 2
quote:
Now future iPhone 6's can have 1,377 hours


I see how you managed to avoid 1337 there.


By w1z4rd on 7/6/2010 9:46:24 AM , Rating: 2
lol

i actually didnt see that one coming - thought we were gona have a seriosu discussion about EVs here

lol


Does it stay?
By tastyratz on 7/6/2010 8:40:20 AM , Rating: 2
While this turned into a powerful battery at such incredibly high pressures, did it stay structurally the same once removed from said pressures?
If so then great!
If not I don't think it will have application outside of the power plant range as a nuclear alternative.




RE: Does it stay?
By AskTheChief on 7/6/2010 8:54:24 AM , Rating: 2
Another thing, when you start using the 'battery' does the structure stay together, or is this a one time use only? What are its thermal properties? Is this new material less likely to blow up or is more stable than a lead acid battery? What does it cost to create this material at the required pressures?


RE: Does it stay?
By manofhorn on 7/6/2010 11:55:29 AM , Rating: 2
apparently this substance shows no hysteresis effects so you could reuse the xenon and fluorine after a compression decompression cycle maintaining similar efficiencies. and there is no reason to compare it to a lead acid battery because unless your car or phone runs on stored mechanical energy then you're out of luck.

now maaaaaybe you could buy a portable generator that could expand the XeF8 while making electricity, but i hesitate to imply applicability.


RE: Does it stay?
By bobsmith1492 on 7/6/2010 12:06:38 PM , Rating: 2
It won't be a "nuclear alternative" power plant! All they did was smash it to store energy. It won't and will never create energy like a nuclear power plant. It can only store it.


Can we store a bolt of lightning yet?
By PAPutzback on 7/6/2010 7:54:52 AM , Rating: 2
Then I'll be impressed.




By fstarnella on 7/6/2010 8:30:58 AM , Rating: 5
1.21 jigawatts!


A viable alternative energy source you say?
By Daniel8uk on 7/6/10, Rating: 0
By InvertMe on 7/6/2010 1:25:18 PM , Rating: 2
...not only found dead but the day after their death their iTunes accounts are suddenly filled with thousands of dollars in purchases. Apple however states this is typical usage and there is no problem or cause of concern (and certainly no cause for a refund since they are dead after all).


By JediJeb on 7/7/2010 12:08:25 AM , Rating: 2
Only if sound is required to make it work.


By pwndcake on 7/6/2010 11:52:19 AM , Rating: 3
You just know some idiot is going to play around with this and the Large Hadron Collider, then it's Hello Combine! I'm going to invest in some crowbars.




Ideal for...
By Qapa on 7/6/2010 8:28:45 AM , Rating: 2
This seems ideal for electric cars... a small battery with loads of energy.

I don't say mobile phones since I don't really know prices or things like that, but for electric cars it would be interesting... 10.000 Km per battery or something would be a real milestone for electric cars to take off... depending, of course, on the price.




Nice....
By Amiga500 on 7/6/2010 8:29:57 AM , Rating: 2
Sounds encouraging. (Although I guess it is similar to things we've all heard in various guises before).

If it can be made practical (with zero radiation emissions), it could be a massive success - a means of efficiently storing variable energy (wind, wave, tidal) for when needed, and also, a portable means of storing energy.

Electric cars, electric planes and electric boats? Could all be made possible.

Of course, there are also massive (positive) implications for space-based electrical power generation for probes sent to the outer reaches of the solar system. Or even those sent to Mars (no delicate solar panels that would get wrecked by sand storms).

Could turn out to be quite the discovery....




Pressure != Energy
By Diesel Donkey on 7/6/2010 10:31:27 AM , Rating: 2
quote:
There was a total of one million atmosphere's of stored energy.


Yeah, I know what the author meant, but the scientist in me feels compelled to point out that one cannot have "atmospheres" of energy as an atmosphere is a unit of pressure (Newtons per meter squared rather than Newton-meters, a.k.a. Joules).




By soxfan on 7/6/2010 2:40:00 PM , Rating: 2
Without reading the article, I am going to take a wild guess and say that the new material is that stuff trapped ever so tightly between Steve Jobs' a$$ cheeks. We already know that Herr Jobs craps gold.




Sounds familiar
By morphologia on 7/6/2010 3:12:00 PM , Rating: 2
Have we finally invented Energon, like in the old Transformers cartoons??




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