 Previous vapor deposition methods left a rough surface which was difficult to work with and destroyed fragile organic molecules attached to the silicon substrate on which it was deposited. (Source: Coll Bau/NIST)
 NIST's new organic molecular switch construction technique not only results in a plausable product, but a much smoother and friendlier gold surface. (Source: Coll Bau/NIST)
A practical molecular switch may be in sight thanks to NIST research.
The inner world of semiconductors is
constantly shrinking, producing faster microchips with more
transistors and multiple cores in the same or an even smaller space
than the previous generations. As a result, technology is starting to
struggle to keep up with Moore's Law. Small breakthroughs are being
made at a good clip by continuously improving technologies like
optical
computing and using new materials like graphene,
but no one is sure where the next great advancement will come
from.
With semiconductors firmly entrenched in 40 nanometer
production fabs and shooting straight for the low 20s, there doesn't
seem like there's very much room left to keep shrinking. However,
before the leap to quantum multi-state or even electron spin
computing, there still lies the frontier of single molecules. Using
single molecules as the tiny switches in microchips has been an idea
kicked around for several years, but as NIST materials scientist
Mariona Coll Bau explains, trying to assemble such chips using the
standard metal vapor deposition technique does not pan out well;
"Imagine what hot steam would do to your arm. Evaporated metal
is much hotter, and organic switching molecules are very fragile—they
can’t stand the heat."
Rather than attaching the
molecules to a silicon surface and then depositing gold vapor and
destroying the molecules, the NIST and University of Maryland team
reversed
the process. They first deposit the gold onto a super-smooth
non-stick surface. This process actually has another benefit aside of
not wreaking havoc on the fragile molecules -- previous deposition
techniques created a very rough metallic surface which could either
destroy the molecules or cause them to not connect to the conductor
at all.
After the gold has cooled, they apply simple overhead
transparencies as a laminate. This allows them to peel the gold from
the non-stick base while leaving the smooth metal surface
intact.
They then attach the molecules to be used as the
switches to the gold conductor's surface and flip the whole thing
over onto a new silicon base. An imprinting machine is used to
compress the layers together without crushing the switches.
And
this technique may not be useful for just future microchip
manufacturing. Coll Bau indicated that it could also be useful for
applications like biosensors, where the electronic world meets the
organic to perform certain tasks.
"We can't expect users to use common sense. That would eliminate the need for all sorts of legislation, committees, oversight and lawyers." -- Christopher Jennings
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