 In nature zinc paraffins act as an antenna, capturing solar energy and transfering it to other complexes to split water. The viruses in the new MIT work grab zinc paraffins, like the one seen here, and use them to split water. (Source: Molbank)
Research raises new hope for a hydrogen economy
One
critical question facing proponents of a hydrogen economy, the term
tossed around for a nation that's switched from fossil fuels
to hydrogen
fuel cells and hydrogen combustion engines, is how to
produce the hydrogen. Current schemes require either expensive
catalysts or require a secondary power source such as solar
power. However, solar power doesn't come cheaply
itself.
Researchers are racing to find a cheaper way to
produce solar energy. One of the top ideas is to borrow from
nature's highly refined solar energy capture system found in plants.
Scientists at MIT are building on past
work, which used naturally occurring chemicals from
photosynthetic organisms to directly convert solar power to split
water and create stored hydrogen gas. The MIT researchers have
upped the ante by creating a virus to automate the difficult assembly
of the necessary chemicals. This could eventually make
biochemical solar cells a viable and less expensive alternative to
traditional panel designs.
Angela Belcher, the Germeshausen
Professor of Materials Science and Engineering and Biological
Engineering, led a team which modified a common, harmless bacterial
virus called M13 to attract and bind with molecules of a catalyst
(the team used iridium oxide) and a biological pigment (zinc
porphyrins).
The bound compounds turned the virus into a
mini-antenna, similar to the molecules found in plants that are
responsible for absorbing water. Energy absorbed by the virus
was able to very efficiently split water in to oxygen and hydrogen
gases.
Left free, the viruses would clump together and stop
efficiently processing water. However, the researchers took the
extra step of embedding them in a hydrogel to prevent clumping.
The
key to this work is that the researchers used a virus to assemble
them. States Professor
Belcher, "We use components people have used before, but we use
biology to organize them for us, so you get better
efficiency."
Thomas Mallouk, the DuPont Professor of
Materials Chemistry and Physics at Pennsylvania State University
comments on the study, "This is an extremely clever piece of
work that addresses one of the most difficult problems in artificial
photosynthesis, namely, the nanoscale organization of the components
in order to control electron transfer rates."
The work
from Belcher's team was published in
the journal Nature
Nanotechnology.
The
next goal is to create a self-sustaining and durable prototype within
the next two years.
With such a prototype, some day it might
be possible to produce pigments in bacteria via viral infection, use
the viruses in this study to assemble the pigments and finally add
the catalyst, to form a quick, biologically produced, and efficient
solar hydrogen production unit.
"So if you want to save the planet, feel free to drive your Hummer. Just avoid the drive thru line at McDonalds." -- Michael Asher
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