Print 13 comment(s) - last by Qapa.. on Apr 21 at 9:35 PM

The nanosponges can be reused as well

Rice University and Penn State University researchers have collaborated to create a sponge capable of soaking up oil spilled in water, which could have a profound impact on the environment.

Daniel Hashim, study leader and graduate student at Rice University, along with Pulickel Ajayan, professor in Mechanical Engineering and Materials Science at Rice University, and Mauricio Terrones, professor of physics, materials science and engineering at Penn State University, are all responsible for the latest creation.

According to the research team, the sponges are made of nanotubes that had a bit of the chemical element boron added to the carbon. By adding boron to the carbon, the nanotubes turned into solid, yet spongy blocks.

Boron is the main secret ingredient behind the nanosponges. By adding boron, the nanotubes grew bends and "elbows" to help produce covalent bonds, which allow the nanosponges to perform the way they do. The sponges are 99 percent air, can be manipulated using magnets, and conduct electricity. They're also superhydrophobic, meaning they float better because they dislike water, and oleophilic, meaning they're attracted to oil.

These nanosponges are capable of soaking up oil and being reused after doing so. According to the team, the nanosponges can undergo about 10,000 compressions where oil is soaked into the sponge, burned off, and returned to the water to soak more. Also, the sponges can hold more than a hundred times their weight in oil.

Nanosponge with boron [Source: Rice University]

"Our goal was to find a way to make three-dimensional networks of these carbon nanotubes that would form a macroscale fabric — a spongy block of nanotubes that would be big and thick enough to be used to clean up oil spills and to perform other tasks,” said Terrones. “We realized that the trick was adding boron — a chemical element next to carbon on the periodic table — because boron helps to trigger the interconnections of the material. To add the boron, we used very high temperatures and we then ‘knitted’ the substance into the nanotube fabric.

"Oil-spill remediation and environmental cleanup are just the beginning of how useful these new nanotube materials could be. For example, we could use these materials to make more efficient and lighter batteries. We could use them as scaffolds for bone-tissue regeneration. We even could impregnate the nanotube sponge with polymers to fabricate robust and light composites for the automobile and plane industries.”

Such nanosponges could come in handy one day for major spills, such as the BP oil spill that occurred in April 2010 when the Deepwater Horizon drilling rig exploded and leaked oil into the Gulf of Mexico for three months. It was described as the "worst spill in U.S. history."

This also isn't the first nanosponge to be used for absorbing oil. In early 2010, Dr. Paul Edmiston of the College of Wooster in Ohio created a glass nanosponge capable of removing oil from water.

Source: Rice University

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if they can ramp it up..
By kattanna on 4/17/2012 12:52:59 PM , Rating: 3
if they can ramp up the production this will be a most useful item.

way to go!

RE: if they can ramp it up..
By ViroMan on 4/17/2012 2:35:21 PM , Rating: 2
1) How expensive is boron?
1a)Would it be economical to make tons of blocks of this stuff to do oil cleanups and be cheaper then current practices?

2)Wasn't there a recent study stating the possible issues of nano pollutions? (they kill cells by piercing them)
2a)If they make tons of this new miracle, will it not create a worse problem?

RE: if they can ramp it up..
By Etsp on 4/17/2012 2:58:07 PM , Rating: 2

1. Apparently $2-$5 per gram.
1a. We will find out if oil companies invest in the technology.

2. It's possible that the negative medical impact of the detergents they currently use may be comparable.

My question is: How well does it work in cold environments? Would it make oil-spill cleanup viable in places like the ocean off Alaska?

RE: if they can ramp it up..
By JediJeb on 4/18/2012 8:38:49 PM , Rating: 2
Boron is used every day by many people in the form of Borax(Sodium Borate) which is used as laundry detergent and also the main ingredient in "Roach Pruf". It is a fairly common element on Earth so it should not be very expensive at all.

Highly purified it may cost $2-$5 per gram, but if they can use it in the Borax form in the process to make the nanotubes then it is pretty much dirt cheap since you can buy 20 Mule Team Borax Laundry Enhancer at $7.90 per 2.15kg or high purity from the chemical supply house at $15 for 500g. Also the Boron Oxide form is almost as cheap for 99%+ purity.

RE: if they can ramp it up..
By FITCamaro on 4/17/2012 2:31:21 PM , Rating: 3

Even if its more expensive, it can't be worse than current oil cleanup methods involving dispersants and non-reusable materials that soak up oil.

RE: if they can ramp it up..
By bah12 on 4/17/2012 4:51:04 PM , Rating: 2
Not to mention, that if this acts as a sponge and rings out. The oil can truly be reclaimed. Solvents/Detergents ruin the oil for actual use. These could be used instead, and the oil would still be marketable thus alleviating some of the higher cost.

RE: if they can ramp it up..
By FITCamaro on 4/18/2012 7:52:13 AM , Rating: 2
Very true.

By chµck on 4/17/2012 2:25:45 PM , Rating: 2
I don't know if betting on oil spills is a good product strategy.

RE: gamblin
By dgingerich on 4/17/2012 3:14:45 PM , Rating: 2
That's like betting on car crashes or crime scene cleanups. There are many businesses out there that do both. Sometimes they have lots of business, sometimes they have downtime.

Despite what you may think, oil spills happen all the time. The big ones make the news, like 20+ car crashes, but there are small ones every day. For instance, when transferring oil from the tankers into trains, pipelines, and/or trucks to transfer the oil to refineries, some is inevitably spilled, and many times into the ocean or local waterway. This would make it cheaper to clean up those small spills.

RE: gamblin
By drycrust3 on 4/17/2012 4:33:59 PM , Rating: 2
The big thing with this is it is magnetic, so after a spill someone can pour this stuff over the spill, then get out an electro-magnet, collect all the stuff with the oil inside, and then put it in a bag for disposal.
The big problem I see with this is it isn't obviously bio-degradable, meaning that if some of it got lost then it could actually be more of a menace to the environment than the oil (or whatever) that it was supposed to save the environment from.

RE: gamblin
By Qapa on 4/21/2012 9:35:19 PM , Rating: 2
Almost right.. "collect the stuff with the oil inside, and then"... squeeze the oil out of it (to still sell the oil to you) and re-use it 9999 more times!!

Also, although being or not biodegradable is a fair concern, it is supposed to be easy to pick up / collect it. So it isn't hard to find either some way to transform it or place it where no harm is done (or less than the oil in the water).

I miss Boron Fishing Rods
By spamreader1 on 4/18/2012 11:30:45 AM , Rating: 2
Any other older fisherman miss them too? Thier sensitivity was and is still unmatched by current fibreglass rods.

RE: I miss Boron Fishing Rods
By JediJeb on 4/18/2012 8:41:36 PM , Rating: 2
I had forgotten those it has been so long since I saw one.

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